| Crystal data |
| Chemical formula |
[Ga(C26H24N3O3)]·C5H5N |
[Ga(C26H24N3O3)]·0.75C2H3N |
[In(C26H24N3O3)]·CH2Cl2
|
|
M
r
|
575.30 |
526.99 |
626.23 |
| Crystal system, space group |
Monoclinic, P21/c
|
Triclinic, P
|
Monoclinic, P21/c
|
| Temperature (K) |
100 |
173 |
100 |
|
a, b, c (Å) |
13.359 (2), 20.413 (3), 9.7470 (15) |
10.9053 (6), 14.1157 (8), 16.2324 (9) |
10.0704 (2), 16.2514 (4), 16.1749 (4) |
| α, β, γ (°) |
90, 98.326 (3), 90 |
93.915 (1), 103.120 (1), 97.600 (1) |
90, 99.130 (2), 90 |
|
V (Å3) |
2629.9 (7) |
2399.6 (2) |
2613.62 (11) |
|
Z
|
4 |
4 |
4 |
| Radiation type |
Mo Kα |
Mo Kα |
Mo Kα |
| μ (mm−1) |
1.09 |
1.18 |
1.14 |
| Crystal size (mm) |
0.24 × 0.12 × 0.10 |
0.24 × 0.24 × 0.20 |
0.34 × 0.14 × 0.07 |
| |
| Data collection |
| Diffractometer |
Bruker SMART APEXII CCD platform |
Bruker SMART APEXII CCD platform |
XtaLAB Synergy, Dualflex, HyPix |
| Absorption correction |
Multi-scan (SADABS; Sheldrick, 1996 ▸) |
Multi-scan (SADABS; Sheldrick, 1996 ▸) |
Multi-scan (CrysAlis PRO; Rigaku OD, 2019 ▸) |
|
T
min, T
max
|
0.645, 0.748 |
0.666, 0.748 |
0.676, 1.000 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
60216, 12727, 7432 |
52020, 20841, 12632 |
31229, 8621, 7401 |
|
R
int
|
0.108 |
0.056 |
0.037 |
| (sin θ/λ)max (Å−1) |
0.833 |
0.806 |
0.768 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.050, 0.120, 1.00 |
0.048, 0.119, 1.00 |
0.029, 0.064, 1.06 |
| No. of reflections |
12727 |
20841 |
8621 |
| No. of parameters |
353 |
653 |
326 |
| No. of restraints |
0 |
12 |
0 |
| H-atom treatment |
H-atom parameters constrained |
H-atom parameters constrained |
H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) |
0.63, −0.60 |
0.62, −0.55 |
0.62, −0.53 |
