Table 5. Experimental details.

Crystal data
Chemical formula	[Mn(C3H7NO)4(H2O)2][Cu5(C7H4NO3)4]·C3H7NO
M r	1374.60
Crystal system, space group	Monoclinic, P21/n
Temperature (K)	100
a, b, c (Å)	19.0669 (9), 14.2943 (6), 19.3450 (8)
β (°)	95.1476 (18)
V (Å3)	5251.2 (4)
Z	4
Radiation type	Mo Kα
μ (mm−1)	2.30
Crystal size (mm)	0.45 × 0.41 × 0.25
Data collection
Diffractometer	Bruker AXS D8 Quest CMOS diffractometer
Absorption correction	Multi-scan (SADABS2016/2; Krause et al., 2015 ▸)
T min, T max	0.582, 0.748
No. of measured, independent and observed [I > 2σ(I)] reflections	87027, 28700, 18767
R int	0.043
(sin θ/λ)max (Å−1)	0.879
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S	0.065, 0.143, 1.07
No. of reflections	28700
No. of parameters	1153
No. of restraints	1810
H-atom treatment	H atoms treated by a mixture of independent and constrained refinement
Δρmax, Δρmin (e Å−3)	2.44, −2.18

Computer programs: APEX3 and SAINT(Bruker, 2016 ▸), SHELXS97 (Sheldrick, 2008 ▸), SHELXL2018/1 (Sheldrick, 2015 ▸), SHELXLE Rev859 (Hübschle et al., 2011 ▸), Mercury (Macrae et al., 2020 ▸) and publCIF (Westrip, 2010 ▸).