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. 2020 May 8;10:7824. doi: 10.1038/s41598-020-64727-5

Table 1.

Pseudo second-order (k) kinetic rate constants for conventional and ultrasonic biosorption of MB onto FBP. Sorption conditions for section A: 5 g/L adsorbent dose, pH 5.8 and different initial concentrations, section B: 50 mg/L initial concentration, pH 5.8 and different adsorbent doses. Correlation factors are also included in the table.

C0 mg/L k (CV) (g/mg.min) R2 k (US) (g/mg.min) R2 % increase in k
Section A 3.6 0.97 ± 0.09 0.997 4.00 ± 0.32 0.992 312
7.0 0.48 ± 0.04 0.979 1.86 ± 0.19 0.997 288
13 0.15 ± 0.01 0.996 0.52 ± 0.04 0.998 254
25 0.10 ± 0.01 0.985 0.35 ± 0.03 0.998 246
50 0.018 ± 0.001 0.996 0.051 ± 0.005 0.995 183
75 0.017 ± 0.001 0.999 0.030 ± 0.002 0.999 79
101 0.012 ± 0.006 0.999 0.016 ± 0.001 0.998 34
Section B Adsorbent Dose (g/L) k (CV) (g/mg.min) R2 k (US) (g/mg.min) R2 % increase in k
1.0 0.0015 ± 0.0001 0.997 0.0015 ± 0.0002 0.996 0
2.5 0.0040 ± 0.0004 0.997 0.0040 ± 0.0003 0.995 0
5.0 0.018 ± 0.001 0.987 0.051 ± 0.004 0.975 183
7.5 0.097 ± 0.007 0.998 0.315 ± 0.020 0.999 225
10 0.102 ± 0.005 0.999 0.398 ± 0.039 0.984 290
Section C pH k (CV) (g/mg.min) R2 k (US) (g/mg.min) R2 % increase in k
2.8 0.013 ± 0.001 0.996 0.017 ± 0.002 0.995 31
3.8 0.026 ± 0.004 0.999 0.037 ± 0.004 0.994 42
5.1 0.034 ± 0006 0.999 0.061 ± 0.006 0.992 79
5.8 0.018 ± 0.005 0.996 0.051 ± 0.005 0.995 183
7.2 0.066 ± 0.006 0.999 0.091 ± 0.006 0.994 38
7.9 0.065 ± 0.006 0.998 0.087 ± 0.006 0.994 34
9.2 0.068 ± 0.008 0.999 0.086 ± 0.008 0.998 26