Table 3.
Spectroscopic parameters of copper(II) complexes with VEGFQ79G and VEGFI83G. [L] = 1 × 10−3 M, 0.8:1 metal to ligand molar ratio at pH 5, 7, and 11.
pH | Ligand | UV/Vis λmax [nm] ε [M−1 cm−1]) |
CD λmax [nm] (Δε[Μ−1 cm−1]) |
---|---|---|---|
7 | VEGFQ79G | 581(134) | 605(−0.52) a; 514(0.75) a; 313(−0.68) b |
7 | VEGFI83G | 600(86) | 605(−0.34) a; 514(0.39) a; 313(−0.28) b |
a d–d Transition. b Nim →Cu2+ charge transfer.