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. 2020 Mar 10;59(19):7561–7568. doi: 10.1002/anie.202000586

Figure 2.

Figure 2

Molecular structures of 2‐R. Hydrogen atoms and the minor component of the disordered i‐Pr group in 2‐C were omitted for clarity. Displacement ellipsoids are drawn at 50 % probability level. Selected bond lengths [Å] and angles [°]: 2‐B: Ga1−Sb1 2.5959(7), Ga1−Cl1 2.2085(13), Sb1−B1 2.245(5), Ga1−Sb1−B1 113.40(14), Sb1−B1−N3 119.5(3), Sb1−B1−N4 133.3(3); 2‐C: Ga1−Sb1 2.6335(3), Ga1−Cl1 2.2178(5), Sb1−C30 2.1716(16), Ga1−Sb1−C30 114.80(4), Sb1−C30−C31 123.17(12), Sb1−C30−C35 117.10(12); 2‐N: Ga1−Sb1 2.6258(3), Ga1−Cl1 2.2213(6), Sb1−N3 2.0502(18), Ga1−Sb1−N3 111.45(5), Sb1−N3−Si1 130.05(10), Sb1−N3−C33 109.17(13).