Table 1.
|
[L(Cl)Ga]2Sb[a] |
2‐B |
2‐C |
2‐N |
---|---|---|---|---|
g 1 |
2.298 |
2.279 |
2.215 |
2.151 |
g 2 |
2.114 |
2.071 |
2.025 |
1.977 |
g 3 |
1.967 |
1.970 |
1.972 |
1.976 |
g iso [b] |
2.126 |
2.107 |
2.071 |
2.035 |
%R |
80 % |
49 % |
28 % |
1 % |
| ||||
121Sb Hyperfine Couplings [MHz][c] | ||||
A 1 |
−385 |
−300 |
−500 |
−651 |
A 2 |
−496 |
−500 |
−560 |
−763 |
A 3 |
1138 |
1240 |
1330 |
1160 |
a iso |
86 |
147 |
90 |
−86 |
T 1 |
−471 |
−447 |
−590 |
−569 |
T 2 |
−582 |
−647 |
−650 |
−677 |
T 3 |
1052 |
1093 |
1240 |
1246 |
| ||||
69Ga hyperfine couplings [MHz][d] | ||||
A 1 |
132 |
173 |
169 |
149 |
A 2 |
176 |
168 |
179 |
166 |
A 3 |
134 |
150 |
169 |
154 |
[a] Data taken from ref. 18. [b] g iso=(g 1+g 2+g 3)/3. [c] Values reported for the 121Sb isotope (gn=1.345), 123Sb hyperfine (gn=0.729) values obtained from the gyromagnetic ratio (A(123Sb)=gn(123Sb)/gn(123Sb)*A(121Sb)), [d] 69Ga isotope (gn=1.344) hyperfine values reported, 71Ga hyperfine value (gn=1.708) obtained from the gyromagnetic ratio.