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. 2020 Mar 10;59(19):7561–7568. doi: 10.1002/anie.202000586

Table 1.

EPR parameters of VI and 2‐R.

[L(Cl)Ga]2Sb[a]

2‐B

2‐C

2‐N

g 1

2.298

2.279

2.215

2.151

g 2

2.114

2.071

2.025

1.977

g 3

1.967

1.970

1.972

1.976

g iso [b]

2.126

2.107

2.071

2.035

%R

80 %

49 %

28 %

1 %

121Sb Hyperfine Couplings [MHz][c]

A 1

−385

−300

−500

−651

A 2

−496

−500

−560

−763

A 3

1138

1240

1330

1160

a iso

86

147

90

−86

T 1

−471

−447

−590

−569

T 2

−582

−647

−650

−677

T 3

1052

1093

1240

1246

69Ga hyperfine couplings [MHz][d]

A 1

132

173

169

149

A 2

176

168

179

166

A 3

134

150

169

154

[a] Data taken from ref. 18. [b] g iso=(g 1+g 2+g 3)/3. [c] Values reported for the 121Sb isotope (gn=1.345), 123Sb hyperfine (gn=0.729) values obtained from the gyromagnetic ratio (A(123Sb)=gn(123Sb)/gn(123Sb)*A(121Sb)), [d] 69Ga isotope (gn=1.344) hyperfine values reported, 71Ga hyperfine value (gn=1.708) obtained from the gyromagnetic ratio.