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. 2020 Jan 31;2020(15-16):1402–1410. doi: 10.1002/ejic.201901278

Scheme 3.

Scheme 3

Synthesis of complex 1L2 by ligand oxidation starting from 1L1 using the 2,4,6‐tert‐butylphenoxy radical and different routes for the synthesis of complex 2L2 by either (electro)chemical N2‐splitting, or via reaction with TMS(N3).