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. 2020 May 6;8:353. doi: 10.3389/fchem.2020.00353

Table 2.

Comparison between the structural properties, synthesis methods, and S resource of BMSs.

Materials Morphology & Size (nm) Synthetic method S resource
NiCo2S4@NC Nanoparticles 9 Hydrothermal TAA
Ni3Co6S8-rGO Plate-shape nanocrystals
Ultrasonic spray pyrolysis Thiourea
NiCo2S4-rGO Hollow prism 500–600 Refluxing & solvothermal TAA
Co1Zn1-S (600) Nanocrystals
Oil-bath & thermally treated TAA
Co8FeS8 Nanocubes 100 Wet chemical bath Thiourea
Co0.5 Fe0.5S2 Nanosphere ~100 Solvothermal Sublimed S
(ZnxCo1−xS QD@HCP) @rGO sponge-like
Thermal-induced sulfidation, carbonization, and reduction reaction Sublimed S
(SnCo)S2/SG Nanocubes 300–400 annealing Sublimed S
(Ni0.3Co0.7)9S8/N-CNTs/rGO Nanoparticles
Coprecipitation/Hydrothermal TAA
CuCo2S4/rGO Nanoparticles 10–50 Solvothermal Thiourea
Ti0.25Sn0.75S2@MWCNTs Lantern-like 750–850 Hydrothermal TAA
CoSnSx@NC Nanoboxes ~150 Solvothermal TAA
N/S-rGO
@ZnSnS3
Hollow
Nano-microcubes ~2,000
Coprecipitation/Hydrothermal Na2S/ Thiourea
Materials Morphology & Size (nm) Synthetic method S resource
VMo2S4-rGO Nanosheet
Solvothermal TAA
ZnSnS3@ rGO Nanoparticles
Solvothermal & Annealing Thiourea
(Co0.5Ni0.5)9S8/NC Nanoparticles & Nanorods
Solvothermal Sulfur powder
Cu2MoS4 Nanoparticles 100 Solvothermal TAA
SnS2/Mn2SnS4/C Nanoboxes 100 Coprecipitation Sulfur powder
CuCo2S4 Sub-microspheres 300–500 Solvothermal Thiourea
NiMo3S4/CT Nanosheets arrays 3,000 Hydrothermal Thiourea
(Fe0.5Ni0.5)9S8 Yolk-shell
Spray pyrolysis Thiourea
Bi0.94Sb1.06S3 Nanorod cluster Hydrothermal TAA
CuV2S4 Nano-polyhedron Solid state reaction Sulfur powder