Table 2.
Comparison between the structural properties, synthesis methods, and S resource of BMSs.
| Materials | Morphology & Size (nm) | Synthetic method | S resource | 
|---|---|---|---|
| NiCo2S4@NC | Nanoparticles 9 | Hydrothermal | TAA | 
| Ni3Co6S8-rGO | Plate-shape nanocrystals —  | 
Ultrasonic spray pyrolysis | Thiourea | 
| NiCo2S4-rGO | Hollow prism 500–600 | Refluxing & solvothermal | TAA | 
| Co1Zn1-S (600) | Nanocrystals —  | 
Oil-bath & thermally treated | TAA | 
| Co8FeS8 | Nanocubes 100 | Wet chemical bath | Thiourea | 
| Co0.5 Fe0.5S2 | Nanosphere ~100 | Solvothermal | Sublimed S | 
| (ZnxCo1−xS QD@HCP) @rGO | sponge-like —  | 
Thermal-induced sulfidation, carbonization, and reduction reaction | Sublimed S | 
| (SnCo)S2/SG | Nanocubes 300–400 | annealing | Sublimed S | 
| (Ni0.3Co0.7)9S8/N-CNTs/rGO | Nanoparticles —  | 
Coprecipitation/Hydrothermal | TAA | 
| CuCo2S4/rGO | Nanoparticles 10–50 | Solvothermal | Thiourea | 
| Ti0.25Sn0.75S2@MWCNTs | Lantern-like 750–850 | Hydrothermal | TAA | 
| CoSnSx@NC | Nanoboxes ~150 | Solvothermal | TAA | 
| N/S-rGO @ZnSnS3  | 
Hollow Nano-microcubes ~2,000  | 
Coprecipitation/Hydrothermal | Na2S/ Thiourea | 
| Materials | Morphology & Size (nm) | Synthetic method | S resource | 
| VMo2S4-rGO | Nanosheet —  | 
Solvothermal | TAA | 
| ZnSnS3@ rGO | Nanoparticles —  | 
Solvothermal & Annealing | Thiourea | 
| (Co0.5Ni0.5)9S8/NC | Nanoparticles & Nanorods —  | 
Solvothermal | Sulfur powder | 
| Cu2MoS4 | Nanoparticles 100 | Solvothermal | TAA | 
| SnS2/Mn2SnS4/C | Nanoboxes 100 | Coprecipitation | Sulfur powder | 
| CuCo2S4 | Sub-microspheres 300–500 | Solvothermal | Thiourea | 
| NiMo3S4/CT | Nanosheets arrays 3,000 | Hydrothermal | Thiourea | 
| (Fe0.5Ni0.5)9S8 | Yolk-shell —  | 
Spray pyrolysis | Thiourea | 
| Bi0.94Sb1.06S3 | Nanorod cluster | Hydrothermal | TAA | 
| CuV2S4 | Nano-polyhedron | Solid state reaction | Sulfur powder |