Table 2.
Parameter | HNT@Ru-1 | HNT@Ru-2 | HNT@Ru-3 |
---|---|---|---|
CO conversion, % | 15.6 | 17.8 | 18.8 |
Ru–time yield × 103, molCO/(molRu s) | 29.3 | 33.4 | 32.1 |
CH4 selectivity, % | 52.8 | 19.9 | 28.8 |
C2–C4 selectivity, % | 20.3 | 1.6 | 3.2 |
C5+ selectivity, % | 26.7 | 78.0 | 67.7 |
CO2 selectivity, % | 0.2 | 0.5 | 0.3 |
% olefins in C5+ | 19.2 | 12.9 | 26.5 |
ASF α | 0.78 | 0.87 | 0.73 |
1 Reaction conditions: P = 1.0 MPa, T = 260 °C, H2/CO = 2:1, gas flow rate = 10 nL/(h gcat); data were collected after 32 h on steam. ASF—Anderson–Schulz–Flory.