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Congestion-induced dendrimer shape changes (I–III) with development of nanocontainer properties for a family of [core: 1,2-diaminoethane]; (4→2); dendri-poly(amidoamine)–(NH2)Z}; (G = 0–10) (PAMAM) dendrimers: Nc = 4; Nb = 2; where, Z–Z=distance between surface groups as a function of generation. Reproduced by permission from [90]. The Royal Society of Chemistry (RSC).
