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. 2020 Apr 21;10(4):642. doi: 10.3390/biom10040642

Table 1.

Historical comparison of Denkewalter, Tomalia and Newkome first divergent, iterative syntheses of dendritic structure.

Tomalia Type Newkome Type Denkewalter Type
Dendritic Topologies Symmetrical, equal branch cell segments Symmetrical, equal branch cell segments Asymmetrical, unequal branch cell segments
1st Patents U.S. #4,507,466 (1985) U.S. #4,289,872 (1981)
1st Public Oral Reports Pauling-Flory Polym. Gordon Conf. (1983) [21]
1st Publications 1st SPSJ Int. Conf., Kyoto, Japan, Abstract (1984)
Polym. J. (Tokyo), (1985) (Full Paper) [11];
Macromolecules (1986) [22]
J. Org. Chem., (1985) (Communication) [24]
Compositional Types poly(amidoamines, amides
imines, phosphorhydrazones,
aryloxys, alkylethers, ureas,
esters, siloxanes, arylenes,
etheramides, triazines,
silanes, carbosilanes, triazoles, thioethers, iminoethers, aryloxyethers, thioether esters, silyloxhydroxyl ethers, alkynes, urethanes, etc.)
poly(amidoethers) poly(L-lysines)
Total Citations (10/23/19)
(Publications & Patents)
45,485 citations
(Google Scholar)
35,519 citations
(Google Scholar)
282 citations [31]