Table 2. Photophysical Properties of Amphiphilic ReO Corroles at 25 °C in Anoxic solutions.
complex | Solvent | λmax,em (nm) | ϕ (%) | τ (μs) |
---|---|---|---|---|
Re[pTCPC](O) | EtOH | 783 | ∼0.03 | 38 (91%), 1.2 (9%) |
Re[pTCPC](O) | EtOH + 3 × 10–3 M NaOH | 777 | ∼0.05 | 27 (73%), 1.0 (27%) |
Re[mTCPC](O) | EtOH | 773 | ∼0.01 | 5.9 (44%), 1.3 (56%) |
Re[mTCPC](O) | EtOH + 3 × 10–3 M NaOH | 766 | ∼0.02 | 13 (23%), 1.7 (77%) |