Table 1. Optical Properties and Electrochemical Properties for o-CbzBiz, m-CbzBiz, and p-CbzBiz.

host	Tm/Tg/Td [oC]	λabsa [nm]	λema [nm]	λphosb [nm]	PLQY [%]	HOMO/LUMOc [eV]	Egd [eV]	ETe [eV]
o-CbzBiz	273/167/371	294, 310	380	491	36	–5.73/–2.17	3.56	2.66
m-CbzBiz	326/na/377	293, 312	380	526	12	–5.74/–2.20	3.54	2.48
p-CbzBiz	296/115/393	294, 327	400	526	88	–5.73/–2.36	3.37	2.45

^aMeasured in toluene at room temperature.

^bMeasured in toluene at 77 K.

^cDetermined by cyclic voltammetry and the onset of the absorption band.

^dThe optical band gap, determined by the onset of the absorption band.

^eCalculated by the highest-energy vibronic transition of the phosphorescence spectra measured at 77 K.