Skip to main content
. 2020 Apr 10;120(9):4056–4110. doi: 10.1021/acs.chemrev.9b00439

Table 1. Comparison of Experimental and Theoretical Energies and Relative Intensities of the Two Rydberg Series Converging to the 4P and 2P Limit of Atomic Oxygen147.

configuration energy expt (eV) energy theory (eV) relative intensity expt relative intensity theory
1s2s22p5(3P) 527.8 528.1 100 100
1s2s22p4(4P)3p 541.3 542.2 6.2 5.1
1s2s22p4(4P)4p 542.6 543.8 1.6 1.9
1s2s22p4(4P)5p 543.2 544.3 0.36 1.1
1s2s22p4(2P)3p 545.6 545.6 5.4 2.0
1s2s22p4(2P)4p 547.2 547.2 1.9 0.5
1s2s22p4(2P)5p 547.7 547.8 0.36 0.24