Figure 2.
Characterization of Cp*Ir(DPL-C16) complex. A) DFT model of Cp*Ir(Cl)(DPL-C16) along with ESI-MS data for the complex (calculated isotopic pattern is shown in red). B) Dynamic light scattering data for Cp*Ir(H)(DPL-C16) (0.02 mM solution in 20% TFE/H2O). C) TEM images showing self-assembled vesicle structures formed by Cp*Ir(H)(DPL-C16). D) A fragment of crystal packing for DPF-C12.