Table 1.
No. | RT | aKI | Components | b% ± SD | cIM | dReferences |
---|---|---|---|---|---|---|
1 | 22.17 | 1003 | α-Phellandrene | 0.02 ± 0.01 | Std | |
2 | 22.75 | 1019 | α-Terpinene | 0.01 ± 0.01 | Std | |
3 | 23.17 | 1025 | m-Cymene | 0.03 ± 0.01 | Std | |
4 | 23.43 | 1028 | (+)-Limonene | 0.02 ± 0.01 | Std | |
5 | 23.56 | 1032 | β-Phellandrene | 0.01 ± 0.01 | Std | |
6 | 24.26 | 1035 | cis-β-Ocimene | 0.01 ± 0.01 | Std | |
7 | 27.37 | 1103 | Nonanal | 0.02 ± 0.01 | Std | |
8 | 31.44 | 1179 | Terpinen-4-ol | 0.02 ± 0.01 | Std | |
9 | 32.14 | 1189 | L-α-Terpineol | 0.01 ± 0.01 | Std | |
10 | 36.24 | 1274 | Phellandral | 0.03 ± 0.01 | MS | NIST |
11 | 39.90 | 1376 | α-Ylangene | 0.24 ± 0.02 | MS | NIST |
12 | 39.95 | 1378 | Isoledene | 0.38 ± 0.02 | MS | NIST |
13 | 40.13 | 1379 | α-Copaene | 1.01 ± 0.03 | Std | |
14 | 40.55 | 1384 | Z-β-Elemene | 0.22 ± 0.03 | Std | |
15 | 41.45 | 1413 | β-Maaliene | 0.40 ± 0.02 | MS-RI | [26] |
16 | 41.72 | 1421 | E-β-Caryophyllene | 1.28 ± 0.04 | Std | |
17 | 41.95 | 1423 | γ-Maaliene | 0.26 ± 0.01 | MS | NIST |
18 | 42.23 | 1441 | cis-α-Ambrinol | 0.51 ± 0.02 | MS | NIST |
19 | 42.35 | 1440 | (+)-Aromadendrene | 3.82 ± 0.21 | MS | NIST |
20 | 42.47 | 1443 | Cedrane | 0.22 ± 0.01 | MS | NIST |
21 | 42.54 | 1451 | cis-Muurola-3,5-diene | 0.51 ± 0.01 | MS | Adams |
22 | 42.64 | 1451 | α-Himachalene | 0.21 ± 0.01 | MS | NIST |
23 | 42.79 | 1452 | trans-Muurola-3,5-diene | 0.27 ± 0.01 | MS | Adams |
24 | 42.88 | 1452 | α-Humulene | 0.44 ± 0.02 | Std | |
25 | 43.04 | 1463 | Alloaromadendrene | 0.74 ± 0.04 | MS | NIST |
26 | 43.40 | 1480 | γ-Muurolene | 8.00 ± 0.22 | MS | [27] |
27 | 43.52 | 1480 | α-Muurolenediastereoisomer | 2.92 ± 0.11 | MS | NIST |
28 | 43.66 | 1484 | Germacrene D | 1.77 ± 0.11 | MS | Adams |
29 | 43.78 | 1493 | (-)-β-Cadinene | 1.20 ± 0.09 | MS | [28] |
30 | 43.98 | 1496 | Ledene (Viridiflorene) | 16.47 ± 0.21 | MS-RI | [29] |
31 | 44.08 | 1501 | α-Muurolene | 5.45 ± 0.12 | MS | [30] |
32 | 44.24 | 1514 | (+)-δ-Cadinene | 1.31 ± 0.05 | Std | |
33 | 44.56 | 1514 | γ-Cadinene | 5.18 ± 0.11 | Std | |
34 | 44.67 | 1523 | (-)-δ-Cadinene | 15.58 ± 0.42 | MS | Adams |
35 | 44.78 | 1527 | trans-Calamenene | 1.60 ± 0.07 | MS | NIST |
36 | 44.83 | 1530 | Epizonarene | 0.90 ± 0.04 | MS-RI | [31] |
37 | 45.08 | 1533 | Cada-1,4-diene | 0.96 ± 0.07 | MS-RI | [32] |
38 | 45.20 | 1540 | α-Muurolenediastereoisomer | 1.82 ± 0.08 | MS | NIST |
39 | 45.36 | 1549 | α-Calacorene | 0.88 ± 0.04 | MS | NIST |
40 | 46.03 | 1568 | Epiglobulol | 1.00 ± 0.05 | MS | NIST |
41 | 46.28 | 1571 | Palustrol | 0.89 ± 0.04 | MS-RI | [33] |
42 | 46.43 | 1578 | (+)-Spathulenol | 0.97 ± 0.04 | Std | |
43 | 46.71 | 1583 | Globulol | 3.10 ± 0.12 | MS | Adams |
44 | 46.95 | 1591 | Viridiflorol (Ledol) | 2.03 ± 0.11 | MS | NIST |
45 | 47.21 | 1599 | Rosifoliol | 1.79 ± 0.08 | MS | NIST |
46 | 47.66 | 1608 | Eudesmol<5epi-7-epi-α> | 1.09 ± 0.07 | MS | Adams |
47 | 47.70 | 1616 | Cubenol | 2.20 ± 0.09 | MS-RI | [34] |
48 | 47.84 | 1619 | (-)-Spathulenol | 0.57 ± 0.04 | Std | |
49 | 48.04 | 1639 | α-epi-Cadinol | 1.65 ± 0.03 | Std | |
50 | 48.09 | 1640 | α-epi-Muurolol | 2.40 ± 0.12 | Std | |
51 | 48.13 | 1646 | (-)-δ-Cadinol | 0.73 ± 0.04 | Std | |
52 | 48.41 | 1654 | α-Cadinol | 3.59 ± 0.09 | Std | |
Total | 96.74 | |||||
Monoterpene hydrocarbons | 0.1 | |||||
Oxygenated monoterpenes | 0.06 | |||||
Sesquiterpene hydrocarbons | 74.04 | |||||
Oxygenated sesquiterpenes | 22.01 | |||||
Others | 0.53 |
Data are the mean of three replicates ± SD.aRetention index (Kovalts) relative to n-alkanes (C9–C22). b Percentage of compounds. c Identification methods (IM): MS by comparison of the Mass spectrum with those of the computer mass libraries Adams, NIST 11 and by interpretation of the mass spectra fragmentations. RI by comparison of retention index with those reported in literature. Std by comparison of the retention time and mass spectrum of available authentic standards. d Papers take as reference to compare the relative RI.