Table 3. Kinetics of Adsorption of Cu2+ on PPy and PPy/GO Composite Electrodesa.
adsorption equation | material | fitting straight line | R2 |
---|---|---|---|
Lagergren first-order equation ln(qe – qt) = ln qe – k1t | PPy | y = 2.883 – 0.0992x | 0.9599 |
PPy/GO | y = 4.518 – 0.1193x | 0.9545 | |
Lagergren second-order equation t/qt = 1/(k2 × qe2) + t/qe | PPy | y = 0.7410 + 0.3640t | 0.9932 |
PPy/GO | y = 0.4365 + 0.0106t | 0.9961 |
qe is the amount of adsorbed ions at equilibrium, mg/g; qt is the amount of adsorbed ions at time t, mg/g; k1 is the first adsorption rate constant, min–1; and k2 is the secondary adsorption rate constant, g/(mg·min).