Table 5.
General band assignments of the fourier transform infrared spectroscopy (FTIR) spectra of the hexane fraction of Kigelia africana fruit extract.
| Characteristic Absorption (cm−1) | %T | Tentative Assignments |
|---|---|---|
| 3700–3584 | 99.27 | Alcohol, O–H Stretching, Medium-Sharp, Free |
| 3550–3200 | 92.98 | Alcohol, O–H Stretching, Strong, Broad, intermolecular bonded |
| 3300–2500 | 82.92 | Carboxylic acid, O–H Stretching, usually centred on 3000 cm−1 |
| 3000–2800 | 90.55 | Amine Salt, N–H Stretching, Strong-Broad |
| 2260–2222 | 98.29 | Nitrile, CΞN stretching, Weak |
| 2160–2120 | 98.06 | Azide, N=N=N stretching, Strong |
| 2065–2083 | 98.1 | N=N anti symmetric stretch or C–N double bond or triple bond |
| 1815–1785 | 97.97 | C=O Stretching, S, |
| 1750–1735 | 87.1 | Esters, C=O Stretching, Strong, 6-membered lactone |
| 1658–1648 | 88.85 | Alkane, C=C stretching, Medium, vinylidene |
| 1653–1624 | 88.79 | C=O stretch in enol form |
| 1639 | 88.07 | N–H in primary amide or C=O β-Ketone of C=O stretch |
| 1629 | 88 | N–H in primary amide |
| 1617 | 89.06 | Vinyl carbon |
| 1610 | 88.56 | Vinyl carbon |
| 1550–1500 | 94.41 | N–O stretching |
| 1508–1534 | 93.07 | Benzene ring in aromatic compounds |
| 1406–1404 | 82.02 | C–N in primary amide |
| 1420–1330 | 81.96 | Alcohol, O–H Bending, Medium |
| 1310–1250 | 81.26 | Aromatic esters, C–O Esters |
| 1342–1266 | 75.6 | Aromatic amine, C–N Stretching |
| 1250–1282 | 75.66 | Ar-O in alky and aryl ethers |
| 669,1124,1171, 1508, 1638 | 95 | p-Coumaric acid |
| 1172 | 74.82 | C–OH in alcohols of C–O stretch |
| 1099–1109 | 65.41 | C–O–H in secondary and tertiary alcohols |
| 1015–1022 | 51.74 | CH–O–H in cyclic alcohols |
| 1044 | 82.4 | Ketone group |
| 1086 | 95 | Aromatic nucleus, C–H relation |
| 905–936 | 74.22 | Carbon ring in cyclic compounds |
| 862–864 | 74.74 | R-NH2 – in primary amine |
| 761 | 67.76 | CH2 out of plane |
| 669 | 57.38 | C–OH in alcohols of C–O–H bending |
| 607 | 50.39 | N–C=O in amides |
FTIR = Fourier Transform Infrared Spectroscopy; %T = %Transmittance.