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. 2020 May 21;6(5):e03989. doi: 10.1016/j.heliyon.2020.e03989

Table 5.

General band assignments of the fourier transform infrared spectroscopy (FTIR) spectra of the hexane fraction of Kigelia africana fruit extract.

Characteristic Absorption (cm−1) %T Tentative Assignments
3700–3584 99.27 Alcohol, O–H Stretching, Medium-Sharp, Free
3550–3200 92.98 Alcohol, O–H Stretching, Strong, Broad, intermolecular bonded
3300–2500 82.92 Carboxylic acid, O–H Stretching, usually centred on 3000 cm−1
3000–2800 90.55 Amine Salt, N–H Stretching, Strong-Broad
2260–2222 98.29 Nitrile, CΞN stretching, Weak
2160–2120 98.06 Azide, N=N=N stretching, Strong
2065–2083 98.1 N=N anti symmetric stretch or C–N double bond or triple bond
1815–1785 97.97 C=O Stretching, S,
1750–1735 87.1 Esters, C=O Stretching, Strong, 6-membered lactone
1658–1648 88.85 Alkane, C=C stretching, Medium, vinylidene
1653–1624 88.79 C=O stretch in enol form
1639 88.07 N–H in primary amide or C=O β-Ketone of C=O stretch
1629 88 N–H in primary amide
1617 89.06 Vinyl carbon
1610 88.56 Vinyl carbon
1550–1500 94.41 N–O stretching
1508–1534 93.07 Benzene ring in aromatic compounds
1406–1404 82.02 C–N in primary amide
1420–1330 81.96 Alcohol, O–H Bending, Medium
1310–1250 81.26 Aromatic esters, C–O Esters
1342–1266 75.6 Aromatic amine, C–N Stretching
1250–1282 75.66 Ar-O in alky and aryl ethers
669,1124,1171, 1508, 1638 95 p-Coumaric acid
1172 74.82 C–OH in alcohols of C–O stretch
1099–1109 65.41 C–O–H in secondary and tertiary alcohols
1015–1022 51.74 CH–O–H in cyclic alcohols
1044 82.4 Ketone group
1086 95 Aromatic nucleus, C–H relation
905–936 74.22 Carbon ring in cyclic compounds
862–864 74.74 R-NH2 – in primary amine
761 67.76 CH2 out of plane
669 57.38 C–OH in alcohols of C–O–H bending
607 50.39 N–C=O in amides

FTIR = Fourier Transform Infrared Spectroscopy; %T = %Transmittance.