Table 5.
Summary of photophysical properties and device performances of the multiple resonance (MR)-thermally activated delayed fluorescence (TADF)-based blue TADF materials.
Emitter |
λmax [nm] |
PLQY |
[eV] |
τd μs |
Host | EQEmax [%] |
CEmax [cdA−1] |
CIE 1931 (x, y) |
References |
---|---|---|---|---|---|---|---|---|---|
DABNA-1 | 460a | 0.88 | 0.18 | 93.7 mCBP (1 wt%) |
mCBP (1 wt%) |
13.5 | 10.6 | (0.13, 0.09) | Hatakeyama et al., 2016 |
DABNA-2 | 469a | 0.90 | 0.14 | 65.3 mCBP (1 wt%) |
mCBP (1 wt%) |
20.2 | 21.1 | (0.12, 0.13) | Hatakeyama et al., 2016 |
B2 | 455b | 0.53 | – | 30.4 PMMA (1 wt%) |
mCBP (1 wt%) |
18.3 | 16.7 | (0.13, 0.11) | Matsui et al., 2018 |
B3 | 441b | 0.33 | – | – | – | – | – | – | Matsui et al., 2018 |
B4 | 450b | 0.57 | – | – | – | – | – | – | Matsui et al., 2018 |
TBN-TPA | 470c | 0.97 | 0.14 | 51.02 DCzppy (4 wt%) |
2,6-DCzppy (4 wt%) |
32.1 | 40.2 | (0.12, 0.19) | Liang et al., 2018 |
t-DABNA | – | 0.85 | 0.17 | 83.3 DPEPO (-wt%) |
DPEPO (5 wt%) |
25.1 | 13.0 | – | Han et al., 2019 |
ν-DABNA | 467d | 0.90 | 0.017 | 4.1 DOBNA-Oar (1 wt%) |
DOBNA-Oar (1 wt%) |
34.4 | 31.0 | (0.12, 0.11) | Kondo et al., 2019 |
ADBNA-Me-Mes | 482d | 0.89 | 0.20 | 165 DOBNA-Oar (1 wt%) |
DOBNA-Oar (1 wt%) |
16.2 | 15.4f | (0.10, 0.27) | Oda et al., 2019 |
ADBNA-Me-Tip | 479d | 0.88 | 0.19 | 147 DOBNA-OAr (1 wt%) |
DOBNA-Oar (1 wt%) |
21.4 | 23.5f | (0.11, 0.29) | Oda et al., 2019 |
Measured in 1 wt% doped film in mCBP host.
Measured in 1 wt% doped film in PMMA host.
Measured in oxygen-free toluene solution (5 × 10−5M).
Measured in 1 wt% doped film in DOBNA-OAr host.
eΔEST = S1-T1.
Current efficiencies at luminance of maximum, 100 cd/m2.