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. 2020 Apr 28;25(9):2058. doi: 10.3390/molecules25092058

Table 2.

Electrochemical parameters of non-chloride and chloride naphthoquinone with tyrosine, valine and tryptophan substituents a.

Compound Epa Epc ΔEp b E1/2 c ipa ipc |ipa/ipc|
(V) (V) (V) (V) (mA cm−2)
3a −1.15 −1.27 0.13 −1.21 0.28 −0.30 0.95
3b −1.16 −1.27 0.12 −1.21 0.28 −0.30 0.95
3c −1.19 −1.30 0.11 −1.24 0.26 −0.27 0.95
4a −1.04 −1.15 0.11 −1.10 0.22 −0.24 0.92
4b −1.05 −1.19 0.14 −1.12 0.21 −0.25 0.83
4c −1.05 −1.17 0.12 −1.11 0.23 −0.27 0.85

a Determined by cyclic voltammetry in TBABF4 0.1 M/DMSO at 100 mV/s. The potentials are given with respect to the Ag/Ag+ pseudo-reference electrode; b ΔEp = Epc − Epa; c E1/2 = (Epa + Epc)/2.