Table 2.
Compound | Epa | Epc | ΔEp b | E1/2 c | ipa | ipc | |ipa/ipc| |
---|---|---|---|---|---|---|---|
(V) | (V) | (V) | (V) | (mA cm−2) | |||
3a | −1.15 | −1.27 | 0.13 | −1.21 | 0.28 | −0.30 | 0.95 |
3b | −1.16 | −1.27 | 0.12 | −1.21 | 0.28 | −0.30 | 0.95 |
3c | −1.19 | −1.30 | 0.11 | −1.24 | 0.26 | −0.27 | 0.95 |
4a | −1.04 | −1.15 | 0.11 | −1.10 | 0.22 | −0.24 | 0.92 |
4b | −1.05 | −1.19 | 0.14 | −1.12 | 0.21 | −0.25 | 0.83 |
4c | −1.05 | −1.17 | 0.12 | −1.11 | 0.23 | −0.27 | 0.85 |
a Determined by cyclic voltammetry in TBABF4 0.1 M/DMSO at 100 mV/s. The potentials are given with respect to the Ag/Ag+ pseudo-reference electrode; b ΔEp = Epc − Epa; c E1/2 = (Epa + Epc)/2.