Principal component analysis showing aged wine samples scores (A) and loadings (B), only loadings with score value > 0.75 were shown. Loadings plot number correspond to: (F1) 2-Butanol, (F2) 1-Butanol, (F3) 1-Pentanol, (F6) 1-Hexanol, (F7) trans-3-Hexenol, (F8) cis-3-Hexenol, (F9) Ethyl acetate, (F10) Isoamyl acetate, (F11) n-Hexyl acetate, (F12) Phenylethyl acetate, (F13) Ethyl butanoate, (F14) Ethyl 3-methylbutanoate, (F15) Ethyl hexanoate, (F16) Ethyl octanoate, (F18) Ethyl lactate, (F19) 3-Methylbutanoic acid, (F20) Hexanoic acid, (F21) Octanoic acid, (F24) Linalool, (F28) α-Terpineol, (F31) β-Citronellol, (F34) 1,4-cineole, (F36) Limonene, (F39) Terpinolene, (F40) β-Damascenone, (F46) 3-oxo-α-Ionol, (F48) 4-Vinyl guaiacol, (F50) Benzyl alcohol, (F52) Methyl vanillate, (F53) Ethyl vanillate, (B3) bound cis-3-Hexenol, (B12) bound Benzyl alcohol, (B14) bound Phenylethyl alcohol, (B15) bound Vanillin, (B18) bound Ethyl vanillate.