Table 5.
Amino acids constituting an odorant and copper-binding site in OR2W1
TMH segmenta | AA position within TMH segmenta | Mutagenesis-validated binding site positions | 2-Phenyl-ethanethiol | 3-Mercaptohexyl acetate | Allyl phenyl acetate | Validated positions in other ORs |
---|---|---|---|---|---|---|
TMH 3 | 8 | bMet1053.33 | Indirect | Indirect | Indirect | His1053.33 [30], His1083.33 [31], Ile1053.33: [64], Met1053.33: [9], His1083.33: [106], Cys1063.33: [50, 98] |
TMH 3 | 12 | bSer1093.37 | Indirect | Indirect | Indirect | Cys1093.37: [30], Asn1093.37: [10, 94], Val1133.37: [107, 123] |
TMH 3 | 15 | bCys1123.40 | Indirect | Indirect | Indirect | Ser1123.40: [10], Ser1133.40: [50, 98, 117], Cys1163.40: [123] |
TMH 6 | 12 | bTyr2526.44 | π-π staking | No interaction | No interaction | Tyr2516.44: [10, 94], Tyr2566.44: [95], Tyr2526.44: [96] |
TMH 6 | 19 | Tyr2596.51 | No interaction | H-bond | H-bond | Tyr2606.51: [64], Tyr2586.51: [64], Tyr2596.51: [97], Tyr2606.51: [50, 98], Ser2636.51: [95] |