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a) Structures of histone acylations from the corresponding acyl-CoA. b) Oxidation of unsaturated fatty acids leads to reactive species that react with histone lysines. COX2 = cyclooxygenase 2. c) Methylglyoxyl (MGO) generated from glycolysis reacts with lysine and arginine residues, eventually leading to advanced glycation products (AGEs) that stimulate inflammatory pathways. DJ-1 = protein/nucleic acid deglycase DJ-1.
