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. 2020 May 29;11:2664. doi: 10.1038/s41467-020-16362-x

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© The Author(s) 2020

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 3 — a Oxocarbenium ions and dioxolenium ions give different diagnostic peaks (in blue). Overview of a comparison of the computed IR-ion spectra (filled blue) and the measured IR-ion spectra (black line) of the glycosyl cations derived from glucosyl (b–d), mannosyl (e–g) and galactosyl (h–j) donors 1–9. Ring-opening of donors 3, 5, 6, and 9 have been presented as accessible structures, their exact conformation is presented in Supplementary Figs. 3, 5, 6, and 9 and coordinates presented in the Supplementary Data file.