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Enthalpy and Gibbs free energy differences for alcoholysis of organotin dicarboxylate in solvent media.
| Complex | toluene |
water |
||
|---|---|---|---|---|
| Enthalpy ΔH [kJ mol−1] | Gibbs Free energy ΔG [kJ mol−1] | Enthalpy ΔH [kJ mol−1] |
Gibbs Free energy ΔG [kJ mol−1] | |
| DMTDA_al_pre-complex (1) | -45.02 | 11.78 | -37.92 | 10.96 |
| DMTDA_al_TS1 (2) | -30.57 | 30.63 | -22.25 | 30.77 |
| DMTDA_al_post-complex (3) | -49.36 | 1.50 | -40.06 | 3.17 |
