Table 8.
Enthalpy and Gibbs free energy differences for the interaction with organotin carbamate with carboxylic acid and alcohol in solvent environment for aliphatic system.
| Complex | Toluene |
Water |
||
|---|---|---|---|---|
| Enthalpy ΔH [kJ mol−1] |
Gibbs Free energy ΔG [kJ mol−1] |
Enthalpy ΔH [kJ mol−1] |
Gibbs Free energy ΔG [kJ mol−1] |
|
| Pre-complex_acid T(33) and W(34) | -97.33 | 13.44 | -90.02 | 15.14 |
| TS13T(35) and W(36) | -103.19 | 13.73 | -92.80 | 15.36 |
| Pre-complex_alcohol T(37) and W(38) | -81.32 | 23.66 | -78.14 | 20.97 |
| TS21T(39) and W(40) | -44.97 | 70.05 | -35.57 | 71.13 |