Table 9.
Enthalpy and Gibbs free energy differences for the interaction with organotin carbamate with carboxylic acid and alcohol in solvent environment for aromatic system.
| Complex | Toluene |
Water |
||
|---|---|---|---|---|
| Enthalpy ΔH [kJ mol−1] |
Gibbs Free energy ΔG [kJ mol−1] |
Enthalpy ΔH [kJ mol−1] |
Gibbs Free energy ΔG [kJ mol−1] |
|
| Pre-complex_acid T(41) and W(42) | -84.99 | 27.56 | -77.19 | 28.24 |
| TS13 T(43) and W(44) | -86.32 | 32.37 | -77.43 | 33.50 |
| Pre-complex_alcohol T(45) and W(46) | -66.69 | 36.44 | -71.49 | 30.29 |
| TS21 T(47) and W(48) | -31.78 | 80.36 | -24.23 | 80.66 |