Table 10.
Tris(2,2’:6,2”-terpyridine)iron(II) perchlorate, 10, electrochemical data (potential in V vs. FcH/FcH+) of the FeII/III redox couple in acetonitrile(CH3CN) with [NBu4][PF6]) as supporting electrolyte, for ca 0.002 mol dm−3 complex solution at the indicated scan rates.
Scan Rate (V/s) | Epa(V) | 106 Ipa (A) | Epc (V) | 106 Ipc (A) | E°’ (V) | ΔE(V) | Ipc/Ipa |
---|---|---|---|---|---|---|---|
0.05 | 0.755 | 22.38 | 0.685 | 21.83 | 0.720 | 0.070 | 0.98 |
0.10 | 0.759 | 28.55 | 0.682 | 27.86 | 0.720 | 0.077 | 0.98 |
0.20 | 0.762 | 42.64 | 0.678 | 41.69 | 0.720 | 0.084 | 0.98 |
0.30 | 0.770 | 53.94 | 0.670 | 52.97 | 0.720 | 0.100 | 0.98 |
0.40 | 0.771 | 67.91 | 0.669 | 66.75 | 0.720 | 0.102 | 0.98 |
0.50 | 0.774 | 73.25 | 0.665 | 72.13 | 0.720 | 0.109 | 0.98 |
1.00 | 0.776 | 110.01 | 0.663 | 106.97 | 0.720 | 0.113 | 0.97 |
2.00 | 0.796 | 135.27 | 0.644 | 130.93 | 0.720 | 0.152 | 0.97 |
5.00 | 0.813 | 198.67 | 0.628 | 192.38 | 0.720 | 0.185 | 0.97 |