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. Author manuscript; available in PMC: 2021 Jan 8.
Published in final edited form as: J Am Chem Soc. 2019 Dec 18;142(1):327–334. doi: 10.1021/jacs.9b10770

Figure 4.

Figure 4.

(a) “Layer-by-layer” assembly strategy for building nanoclusters that are modularly extended in size. (b) 31P{1H} NMR spectrum of [21][SbF6]10. (c) Synthetic scheme for reactions of [21][SbF6]10 and thiol-containing substrates. (d) Substrate scope for conjugation reactions. All cluster conjugates were observed in situ by ESI-MS(–) (See SI Section S2.27 for full scope and characterization data).