Table 4.
Solubility constants for hydrous, amorphous Pu(IV) solids and Pu4+ hydrolysis constants in the ThermoChimie database
Reaction | log K0 or βn0 | Reference |
---|---|---|
Pu(OH)4(am) + 4 H+ ⇌ Pu4+ + 4 H2O | −0.80 ± 1.3 | Lemire and Garisto (1989), from Rai (1984) |
PuO2·2H2O(am) + 4 H+ ⇌ Pu4+ + 4 H2O | −2.37 ± 0.52 | NEA-TDB: Guillaumont et al. (2003) |
Pu4+ + H2O ⇌ PuOH3+ + H+ | 0.60 ± 0.20 | NEA-TDB: Guillaumont et al. (2003) |
Pu4+ + 2 H2O ⇌ Pu(OH)22+ + 2 H+ | 0.60 ± 0.30 | NEA-TDB: Guillaumont et al. (2003) |
Pu4+ + 3 H2O ⇌ Pu(OH)3+ + 3 H+ | −2.30 ± 0.40 | NEA-TDB: Guillaumont et al. (2003) |
Pu4+ + 4 H2O ⇌ Pu(OH)40 + 4 H+ | −8.5 ± 0.50 | NEA-TDB Guillaumont et al. (2003) |