. Author manuscript; available in PMC: 2021 Jun 8.

Published in final edited form as: Angew Chem Int Ed Engl. 2020 Apr 1;59(24):9594–9600. doi: 10.1002/anie.202000532

Table 4.

Scope of ArI^[a,b]

^[a]

Conditions: 1a (0.2 mmol, 2.0 equiv), aryl iodide 2 (1.0 equiv), Pd(OAc)₂ (10 mol %), TDG3 (30 mol %), L12 (40 mol %), TFA (1.5 equiv), Ag₃PO₄ (1.0 equiv), HFIP (0.6 mL), 100 °C, under air, 24 h.

^[b]

Isolated yields.

^[c]

1a (0.1 mmol, 1.0 equiv), aryl iodide 2 (2.0 equiv).

^[d]

TDG6.

^[e]

L12 (1.0 equiv), 48 h.

^[f]

TFA (0.5 equiv).