Table 1. 13C NMR (150 MHz) Spectroscopic Data for Compounds 1–5 in CD3ODa.
no. | 1 | 2 | 3 | 4 | 5 |
---|---|---|---|---|---|
1 | 210.7 | 213.0 | 206.2 | 205.8 | 206.9 |
2 | 39.9 | 43.2 | 127.6 | 127.6 | 128.7 |
3 | 77.6 | 69.3 | 142.7 | 142.3 | 144.5 |
4 | 73.7 | 78.4 | 76.0 | 35.2 | 36.6 |
5 | 63.5 | 64.7 | 73.4 | 76.5 | 78.3 |
6 | 58.6 | 60.7 | 73.4 | 73.1 | 75.4 |
7 | 24.1 | 27.1 | 27.8 | 27.8 | 28.8 |
8 | 35.0 | 34.0 | 35.7 | 33.5 | 34.7 |
9 | 38.0 | 41.8 | 35.3 | 34.4 | 33.2 |
10 | 52.1 | 52.0 | 51.6 | 51.6 | 55.5 |
11 | 20.2 | 21.8 | 23.0 | 22.1 | 22.5 |
12 | 32.9 | 37.5 | 32.3 | 32.8 | 36.7 |
13 | 50.3 | 54.4 | 44.2 | 43.2 | 54.0 |
14 | 81.3 | 82.2 | 81.1 | 82.0 | 79.4 |
15 | 83.4 | 88.4 | 82.6 | 83.4 | 211.5 |
16 | 121.1 | 39.9 | 32.9 | 33.3 | 129.8 |
17 | 161.6 | 86.7 | 52.2 | 51.9 | 189.4 |
18 | 14.8 | 21.2 | 14.1 | 15.0 | 19.9 |
19 | 13.3 | 15.0 | 14.0 | 13.0 | 14.4 |
20 | 35.0 | 83.7 | 78.6 | 79.4 | 38.2 |
21 | 16.8 | 15.0 | 10.9 | 19.8 | 17.6 |
22 | 79.9 | 80.6 | 78.6 | 77.0 | 81.0 |
23 | 27.1 | 33.9 | 32.3 | 28.6 | 34.5 |
24 | 152.8 | 153.9 | 152.8 | 153.1 | 152.5 |
25 | 120.8 | 121.7 | 120.2 | 120.2 | 122.2 |
26 | 167.7 | 169.6 | 168.4 | 168.8 | 168.7 |
27 | 10.5 | 9.2 | 8.6 | 10.3 | 12.4 |
28 | 60.2 | 21.4 | 19.1 | 18.5 | 20.4 |
CH3CO-1′ | 170.1 | 171.4 | 170.1 | 171.0 | |
CH3CO-2′ | 19.9 | 20.5 | 19.9 | 19.1 | |
OMe | 52.1 |
Chemical shifts are in ppm, and the assignments were based on HSQC, HMBC, and NOSEY spectra.