Table 2. Experimental details.

Crystal data
Chemical formula	C6H7BrN+·NO3 −
M r	235.04
Crystal system, space group	Monoclinic, P21/c
Temperature (K)	293
a, b, c (Å)	9.7123 (8), 23.4964 (19), 7.6264 (6)
β (°)	97.052 (4)
V (Å3)	1727.2 (2)
Z	8
Radiation type	Mo Kα
μ (mm−1)	4.73
Crystal size (mm)	0.42 × 0.18 × 0.12
Data collection
Diffractometer	Bruker SMART APEXII CCD
Absorption correction	Multi-scan (SADABS; Sheldrick, 1996 ▸)
T min, T max	0.374, 0.567
No. of measured, independent and observed [I > 2σ(I)] reflections	16821, 4609, 2355
R int	0.058
(sin θ/λ)max (Å−1)	0.684
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S	0.059, 0.183, 1.02
No. of reflections	4609
No. of parameters	218
H-atom treatment	H-atom parameters constrained
Δρmax, Δρmin (e Å−3)	0.68, −0.84

Computer programs: APEX2 and SAINT (Bruker, 2004 ▸), SHELXT (Sheldrick, 2015a ▸), SHELXL2017 (Sheldrick, 2015b ▸), ORTEP-3 for Windows and WinGX (Farrugia, 2012 ▸), PLATON (Spek, 2020 ▸), Mercury (Macrae et al., 2020 ▸) and publCIF (Westrip, 2010 ▸).