| Cu1—N1 | 2.0241 (9) | N22—C23 | 1.4580 (13) |
| Cu1—N22 | 2.0374 (8) | C23—H23A | 0.98 |
| Cu1—Cl2 | 2.2500 (3) | C23—H23B | 0.98 |
| Cu1—Cl1i | 2.2835 (3) | C23—H23C | 0.98 |
| Cu1—Cl1 | 2.6112 (3) | C3—C4 | 1.3953 (15) |
| N1—C6 | 1.3320 (12) | C3—H3 | 0.95 |
| N1—C2 | 1.3561 (12) | C4—C5 | 1.3867 (15) |
| C2—C3 | 1.3842 (14) | C4—H4 | 0.95 |
| C2—C21 | 1.4663 (14) | C5—C6 | 1.3953 (14) |
| C21—N22 | 1.2796 (13) | C5—H5 | 0.95 |
| C21—H21 | 0.95 | C6—H6 | 0.95 |
| N1—Cu1—N22 | 80.20 (3) | C21—N22—Cu1 | 114.21 (7) |
| N1—Cu1—Cl2 | 92.29 (2) | C23—N22—Cu1 | 126.45 (7) |
| N22—Cu1—Cl2 | 155.16 (3) | N22—C23—H23A | 109.5 |
| N1—Cu1—Cl1i | 173.79 (2) | N22—C23—H23B | 109.5 |
| N22—Cu1—Cl1i | 93.61 (3) | H23A—C23—H23B | 109.5 |
| Cl2—Cu1—Cl1i | 93.600 (11) | N22—C23—H23C | 109.5 |
| N1—Cu1—Cl1 | 88.81 (3) | H23A—C23—H23C | 109.5 |
| N22—Cu1—Cl1 | 94.79 (3) | H23B—C23—H23C | 109.5 |
| Cl2—Cu1—Cl1 | 108.803 (10) | C2—C3—C4 | 118.02 (9) |
| Cl1i—Cu1—Cl1 | 91.137 (10) | C2—C3—H3 | 121 |
| Cu1i—Cl1—Cu1 | 88.864 (11) | C4—C3—H3 | 121 |
| C6—N1—C2 | 118.79 (8) | C5—C4—C3 | 119.36 (9) |
| C6—N1—Cu1 | 127.36 (7) | C5—C4—H4 | 120.3 |
| C2—N1—Cu1 | 113.81 (6) | C3—C4—H4 | 120.3 |
| N1—C2—C3 | 122.78 (9) | C4—C5—C6 | 118.99 (10) |
| N1—C2—C21 | 113.95 (8) | C4—C5—H5 | 120.5 |
| C3—C2—C21 | 123.26 (9) | C6—C5—H5 | 120.5 |
| N22—C21—C2 | 117.82 (8) | N1—C6—C5 | 122.05 (9) |
| N22—C21—H21 | 121.1 | N1—C6—H6 | 119 |
| C2—C21—H21 | 121.1 | C5—C6—H6 | 119 |
| C21—N22—C23 | 119.31 (9) | ||
| C6—N1—C2—C3 | −0.69 (15) | N1—C2—C3—C4 | 1.35 (16) |
| Cu1—N1—C2—C3 | −178.63 (8) | C21—C2—C3—C4 | −177.87 (10) |
| C6—N1—C2—C21 | 178.59 (9) | C2—C3—C4—C5 | −0.67 (16) |
| Cu1—N1—C2—C21 | 0.66 (11) | C3—C4—C5—C6 | −0.57 (17) |
| N1—C2—C21—N22 | −0.97 (14) | C2—N1—C6—C5 | −0.66 (15) |
| C3—C2—C21—N22 | 178.31 (10) | Cu1—N1—C6—C5 | 176.97 (8) |
| C2—C21—N22—C23 | −177.41 (9) | C4—C5—C6—N1 | 1.29 (17) |
| C2—C21—N22—Cu1 | 0.77 (12) |