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. 2020 May 15;13(10):2284. doi: 10.3390/ma13102284

Table 1.

Summary of the papers related to the use of stone waste/minerals in alkali activation processes. A classification of the minerals based on their chemical nature (alumino-silicate or carbonate) is provided, in addition to the composition of the ‘active’ raw materials for alkali activation (if any) and the general composition of the liquid alkaline activator.

Classification Mineral Additive Alkali-Activation Source Activator Reference
Alumino-silicates Granite Fly Ash/Granulated Blast Furnace Slag NaOH + Na2SiO3 + H2O [47]
Granite Metakaolin NaOH + Na2SiO3 + H2O [48]
Granite - NaOH + Na2SiO3 + H2O [46]
Albite + - Na2CO3/NaOH [49]
Pietra Serena Metakaolin NaOH + Na2SiO3 + H2O [50]
Pisha sandstone -/Fly Ash NaOH + Na2SiO3 + H2O [51]
Pisha sandstone - NaOH + NaCO3 + Na2SO4 + Na2SiO3 + H2O [52]
Cordierite Metakaolin NaOH + Na2SiO3 + H2O [53]
Diatomite - NaOH + H2O + Wood Biomass Ash ^ [54]
Carbonates Calcite Metakaolin NaOH + Na2SiO3 + H2O [55]
Calcite Granulated Blast Furnace Slag NaOH + H2O [56]
Calcite Metakaolin NaOH/KOH + Na2SiO3 + H2O [57]
Calcite Fly Ash NaOH + Na2SiO3 + H2O [58]
Dolomite Fly Ash/Granulated Blast Furnace Slag Na2CO3/NaOH [59]
Dolomite Metakaolin NaOH + Na2SiO3 + H2O [55]
Dolomite + Bentonite + Na2CO3 H2O [60]
Dolomite + Granulated Blast Furnace Slag + Na2CO3 H2O [61]
Dolomite Fly ash/cement NaOH + Na2SiO3 + H2O [62]
Marble ° - NaOH + H2O [63]
Marble - NaOH + Na2SiO3 + H2O [45]
Marble Smectite clay NaOH + Na2SiO3/Sodium citrate + H2O [64]
Marble Cement/Fly ash/GBFS/Gypsum/Clay NaOH + Na2SiO3 + H2O [65]
Marble Fly ash NaOH + Na2SiO3 + H2O [66]
Pietra di Angera Metakaolin NaOH + Na2SiO3 + H2O [50]
Travertine ° - NaOH + H2O [63]
Limestone Metakaolin NaOH + H2O [67]
Limestone Fly Ash/Granulated Blast Furnace Slag NaOH + Na2SiO3 + H2O [68]
Limestone Granulated Blast Furnace Slag Na2CO3 + H2O [69,70]
Limestone - NaOH + Na2SiO3 + H2O [40]
Limestone Halloysite clay NaOH + Na2SiO3+H2O [71]
Limestone * Granulated Blast Furnace Slag NaOH + Na2CO3 + H2O [72]
Mixed Dolomite + Microcline + Albite + Quartz - NaOH + Na2SiO3 + H2O [46]
Marl + - NaOH + Na2SiO3 + H2O [73]
Marl ++Limestone - Na2SiO3 + H2O [74]
Marl/Marl + Granulated Blast Furnace Slag Na2SiO3 + H2O [75]
Pietra serena sludge Fly ash/metakaolin NaOH + H2O [76]
Garnet tailings Metakaolin Na2SiO3 + NaOH + H2O [77]

* Calcite + Dolomite/Calcite/Calcite + Quartz. ° Marble and Travertine were used in combination with Tuff. + Calcined. ^ Mainly calcium carbonate.