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Proposed mechanism of oleocanthal (5) and oleacein (6) formation, starting from ligstroside (3) or oleuropein (4) through oleokoronal (9) or oleomissional (10). Hydroxytyrosol (1), tyrosol (2), ligstroside aglycon monoaldehydic form (7), and oleuropein aglycon monoaldehydic form (8) are also represented.
