. Author manuscript; available in PMC: 2020 Jun 12.

Published in final edited form as: J Chem Eng Data. 2019 Apr 1;64(4):1399–1413. doi: 10.1021/acs.jced.8b00977

Table 10.

Experimental and Correlated Mole Fraction Solubility of WS·IPA (x₁) in the Ternary Solvent Mixture of IPA (2) + Acetone (3) with w₃ = 0.095 + Hexane (4) at Different Temperatures, T, and at Pressure, p = 101.3 kPa^a

		Apelblat		λh				Apelblat		λh
T/K	10³ $x_{1}^{exp}$	10³ $x_{1}^{cal}$	10² RD	10³ $x_{1}^{cal}$	10² RD	T/K	10³ $x_{1}^{exp}$	10³ $x_{1}^{cal}$	10² RD	10³ $x_{1}^{cal}$	10² RD
w₄ = 0.086						w₄ = 0.174
280.1	1.52	1.54	−1.32	1.58	−4.15	279.8	1.03	1.02	0.92	1.06	−3.28
285.8	1.81	1.78	1.49	1.79	0.86	281.0	1.07	1.06	0.67	1.10	−2.77
291.5	2.04	2.04	0.01	2.03	0.83	285.8	1.21	1.23	−1.54	1.24	−2.43
304.2	2.68	2.69	−0.36	2.64	1.44	296.5	1.66	1.65	0.24	1.62	2.59
312.4	3.14	3.14	−0.01	3.12	0.89	303.7	1.96	1.97	−0.70	1.91	2.13
320.8	3.63	3.63	0.07	3.68	−1.14	312.6	2.40	2.38	0.79	2.35	2.42
						322.7	2.87	2.88	−0.23	2.93	−2.15
w₄ = 0.272						w₄ = 0.366
279.8	0.87	0.87	−0.06	0.86	1.31	279.4	0.54	0.56	−2.35	0.56	−3.51
286.3	0.99	0.99	0.49	0.98	0.61	287.6	0.67	0.67	0.45	0.67	0.45
293.4	1.12	1.13	−0.77	1.14	−1.38	294.5	0.80	0.78	2.96	0.77	3.52
299.1	1.26	1.26	0.12	1.27	−0.64	311.6	1.07	1.09	−2.12	1.09	−1.59
307.9	1.51	1.50	0.67	1.51	0.28	315.6	1.17	1.18	−0.27	1.18	−0.07
312.6	1.64	1.65	−0.66	1.65	−0.59	321.6	1.32	1.31	0.88	1.32	0.36
315.9	1.76	1.76	0.20	1.75	0.69
w₄ = 0.468
281.1	0.33	0.33	−0.89	0.33	−2.36
284.3	0.36	0.36	0.73	0.36	0.14
301.5	0.56	0.56	0.59	0.55	1.94
311.4	0.69	0.70	−1.64	0.70	−0.99
315.0	0.77	0.76	1.31	0.75	1.36
318.9	0.82	0.82	−0.23	0.82	−1.01

Standard uncertainty, u, is u(T) = 2 K. Relative standard uncertainties, u_r are u_r(p) = 0.1, u_r(x₁) = 0.01, u_r(w₃) = 0.001, and u_r(w₄) = 0.003. $x_{1}^{exp}$ refers to the experimental mole fraction solubility. $x_{1}^{cal}$ refers to the calculated solubility data using the Apelblat and λh model equations. RD represents the corresponding relative deviation. w₃ is the mass fraction of acetone (3) in binary IPA (2) + acetone (3) mixture. w₄ is the mass fraction of hexane (4) in ternary IPA (2) + acetone (3) + hexane (4) mixture.