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. Author manuscript; available in PMC: 2020 Jun 12.
Published in final edited form as: J Am Chem Soc. 2020 May 5;142(20):9112–9118. doi: 10.1021/jacs.0c03039

Figure 3.

Figure 3.

Scope of the Trp photobioconjugation process. a % conversion was measured by TIC, average of 2 runs. b [1a] = 2 mM. c 150 min reaction, [GSH] = 5 mM, [1a] = 10 mM. d Isolated after HPLC purification, average of two experiments. e 20 mM 1a. f Tris(2-carboxyethyl)phosphine (TCEP) (1 mM) used as an additive.