Unactivated Alkene Reactivitya
a(BT)S directed reaction run with the following conditions: starting material (0.10 mmol), Alkene (1.2 equiv), AgOAc (3 equiv) Benzoqui-none (0.5 equiv), Pd(OAc)2 (10 mol%), tAmylOH (1 ml), Boc-L-phenylalanine (0.2 equiv), DMSO (7 equiv), 4Å molecular sieves, 75 °C, air, 6 h; other reactions run both under above conditions and under originally reported conditions.