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. Author manuscript; available in PMC: 2020 Sep 6.
Published in final edited form as: ACS Catal. 2019 Jul 2;9(9):7626–7640. doi: 10.1021/acscatal.9b01471

Scheme 9.

Scheme 9.

Unactivated Alkene Reactivitya

a(BT)S directed reaction run with the following conditions: starting material (0.10 mmol), Alkene (1.2 equiv), AgOAc (3 equiv) Benzoqui-none (0.5 equiv), Pd(OAc)2 (10 mol%), tAmylOH (1 ml), Boc-L-phenylalanine (0.2 equiv), DMSO (7 equiv), 4Å molecular sieves, 75 °C, air, 6 h; other reactions run both under above conditions and under originally reported conditions.