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. 2020 Apr 17;10(10):5814–5820. doi: 10.1021/acscatal.0c00690

Scheme 5. Biologically Active Sulfoxide Reduction,

Scheme 5

Reaction conditions: sulfoxide (0.30 mmol), fac-Ir(ppy)3 (1 mol %), PPh3 (0.36 mmol) in CH2Cl2 (1.5 mL) at RT.

1H NMR yields reported based on a trimethoxybenzene internal standard and isolated yields of products after column chromatography are shown in parentheses.

48 h reaction time.

24 h reaction time.