Scheme 5. Alkyl Nitrile Solvent as a Nucleophile.
Conditions: olefin (0.5 mmol, 1 equiv), TBPB (2 equiv), Ir(ppy)3 (2 mol %), aldehyde (5 equiv), alkyl nitrile (5 mL), white LED light, 65 °C, 20 h.
On a 0.1 mmol scale.
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