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. 2020 Mar 24;142(14):6538–6547. doi: 10.1021/jacs.9b10430

Figure 10.

Figure 10

(a) Photoswitching of di-ortho-fluoro di-ortho-chloro azobenzene (8). UV–vis spectra of 8: (b) 50 μM in DMSO is used to show the full spectrum; (c) 500 μM in DMSO and 9:1 DMSO:H2O are used to visualize the extent of the n → π* band tails; and (d) X-ray structure of trans-8x and its calculated vertical excitation energy (TD-PBE0/def2-TZVP).