Table 3. Photophysical Properties of Re-imido Corroles at 77 K in a 4:6 v/v Toluene/THF Frozen Glass.
complex | λmax,ex (nm) | λmax,em (nm) | Φ, % | τ (μs, % contribution) |
---|---|---|---|---|
Re[TPC](NPh) | 437, 544, 578 | 754 | 2.8 | 41 (31%); 91 (69%) |
Re[TpCF3PC](NPh) | 438, 544, 577 | 749 | 3.4 | 47 (34%); 108 (66%) |
Re[TpOCH3PC](NPh) | 440, 546, 583 | 761 | 3.1 | 45 (34%); 89 (66%) |