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. 2020 Apr 10;59(9):6382–6389. doi: 10.1021/acs.inorgchem.0c00477

Table 3. Photophysical Properties of Re-imido Corroles at 77 K in a 4:6 v/v Toluene/THF Frozen Glass.

complex λmax,ex (nm) λmax,em (nm) Φ, % τ (μs, % contribution)
Re[TPC](NPh) 437, 544, 578 754 2.8 41 (31%); 91 (69%)
Re[TpCF3PC](NPh) 438, 544, 577 749 3.4 47 (34%); 108 (66%)
Re[TpOCH3PC](NPh) 440, 546, 583 761 3.1 45 (34%); 89 (66%)