Table 1. Summary for the Dehydration of Hexose Sugars under Aqueous Conditions by Using the Acidic Ion Exchange Catalystc.
run | asugar, mmol | bsalt, (w/w) | temp. (°C) | cat. (w/w) | time (h) | conversion (%) | yield (%) LA |
---|---|---|---|---|---|---|---|
1 | fructose, 1.1 | NaCl, 1 | 110 | 0.3 | 12 | 100 | 74.6 |
2 | fructose, 1.1 | KCl, 1.27 | 110 | 0.3 | 12 | 100 | 76.7 |
3 | fructose, 1.1 | CaCl2, 2.5 | 110 | 0.3 | 12 | 100 | 64.8 |
4 | fructose, 1.1 | Na2CO3, 1.8 | 110 | 0.3 | 12 | 78.1 | 16.8 |
5 | fructose, 1.1 | Na2SO4, 2.14 | 110 | 0.3 | 12 | 35.3 | 14.1 |
6 | fructose, 1.1 | None | 110 | 0.3 | 12 | 41.5 | 21.1 |
7 | fructose, 1.1 | NaCl, 0.5 | 110 | 0.3 | 12 | 99.2 | 74.9 |
8 | fructose, 1.1 | NaCl, 2 | 110 | 0.3 | 12 | 100 | 78.9 |
9 | fructose, 1.1 | NaCl, 1 | 95 | 0.3 | 24 | 84.1 | 52.8 |
10 | fructose, 1.1 | NaCl, 1 | 130 | 0.3 | 6 | 100 | 77.1 |
11 | fructose, 0.55 | NaCl, 1 | 110 | 0.3 | 24 | 100 | 79.8 |
12 | fructose, 0.88 | NaCl, 1 | 110 | 0.3 | 24 | 100 | 76.5 |
13 | fructose, 0.2 | NaCl, 1 | 110 | 0.3 | 24 | 100 | 53.8 |
14 | fructose, 1.1 | NaCl, 1 | 110 | 0.1 | 24 | 99.4 | 53.4 |
15 | fructose, 1.1 | NaCl, 1 | 110 | 0.2 | 24 | 99.7 | 65.5 |
16 | fructose, 1.1 | NaCl, 1 | 110 | 0.4 | 12 | 100 | 75.1 |
17 | glucose, 1.1 | NaCl, 1 | 130 | 0.3 | 24 | 65.6 | 34.4 |
18 | glucose, 1.1 | NaCl, 1 | 145 | 0.3 | 24 | 100 | 70.7 |
19 | glucose, 1.1 | none | 145 | 0.3 | 24 | 62.3 | 27.6 |
Sugar amounts in 2 mL aqueous solution.
Salt ratio to sugar (w/w).
Catalyst ratio to sugar (w/w).