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. 2020 Jun 11;5(24):14275–14282. doi: 10.1021/acsomega.9b04406

Table 1. Summary for the Dehydration of Hexose Sugars under Aqueous Conditions by Using the Acidic Ion Exchange Catalystc.

run asugar, mmol bsalt, (w/w) temp. (°C) cat. (w/w) time (h) conversion (%) yield (%) LA
1 fructose, 1.1 NaCl, 1 110 0.3 12 100 74.6
2 fructose, 1.1 KCl, 1.27 110 0.3 12 100 76.7
3 fructose, 1.1 CaCl2, 2.5 110 0.3 12 100 64.8
4 fructose, 1.1 Na2CO3, 1.8 110 0.3 12 78.1 16.8
5 fructose, 1.1 Na2SO4, 2.14 110 0.3 12 35.3 14.1
6 fructose, 1.1 None 110 0.3 12 41.5 21.1
7 fructose, 1.1 NaCl, 0.5 110 0.3 12 99.2 74.9
8 fructose, 1.1 NaCl, 2 110 0.3 12 100 78.9
9 fructose, 1.1 NaCl, 1 95 0.3 24 84.1 52.8
10 fructose, 1.1 NaCl, 1 130 0.3 6 100 77.1
11 fructose, 0.55 NaCl, 1 110 0.3 24 100 79.8
12 fructose, 0.88 NaCl, 1 110 0.3 24 100 76.5
13 fructose, 0.2 NaCl, 1 110 0.3 24 100 53.8
14 fructose, 1.1 NaCl, 1 110 0.1 24 99.4 53.4
15 fructose, 1.1 NaCl, 1 110 0.2 24 99.7 65.5
16 fructose, 1.1 NaCl, 1 110 0.4 12 100 75.1
17 glucose, 1.1 NaCl, 1 130 0.3 24 65.6 34.4
18 glucose, 1.1 NaCl, 1 145 0.3 24 100 70.7
19 glucose, 1.1 none 145 0.3 24 62.3 27.6
a

Sugar amounts in 2 mL aqueous solution.

b

Salt ratio to sugar (w/w).

c

Catalyst ratio to sugar (w/w).