Table 2. Scope of the Bi-Catalyzed Oxidative Coupling of Arylboronic Acids and Sodium Triflate^a.

^aReaction conditions: 1 (0.3 mmol), NaOTf (0.33 mmol), 4c (0.03 mmol), [Cl₂pyrF]BF₄ (0.33 mmol), Na₃PO₄ (0.6 mmol), and 5 Å MS (120 mg) in CHCl₃ at 60 °C for 16 h. Yields of isolated pure material.

^bReaction performed at 90 °C with 2.0 equiv of NaF as base.

^cYields determined by ¹⁹F NMR using 1-fluoro-4-nitrobenzene as internal standard.

^dReactions performed at 0.025 mmol of the corresponding arylboronic acids.

^eReaction performed at 90 °C with 4.0 equiv of Na₃PO₄ as base.