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. 2020 Feb 20;83(2):268–276. doi: 10.1021/acs.jnatprod.9b00655

Table 1. 13C NMR Data of Compounds 15 (Methanol-d4, T = 298 K, δ ppm).

position 1a 2b 3b 4b 5b
1 133.91 132.32 132.30 132.29 132.30
1a 129.50 130.39 130.20 130.21 130.37
2 155.84 156.31 156.35 156.35 156.31
3 122.06 121.70 121.81 121.81 121.69
4 129.97 129.95 129.98 129.97 129.95
4a 131.07 130.94 131.10 131.09 130.95
5 156.81 156.73 156.74 156.75 156.71f
5a 118.00 118.15 118.12 118.13 118.13
6 107.65 107.62 107.60 107.65 107.67g
7 157.65 157.44 157.78 157.61 157.47e
8 121.19 120.83 120.96 120.97 120.95c
8a 131.23 131.14 130.94 130.95c 130.91h
9 192.01 n. o. 192.38 192.44d 192.68d
10 192.77 192.06 193.57 193.68 193.81
11 23.07 31.26 31.84 31.22 31.25
12 44.21 50.13 50.02 50.04 50.12
13 71.98 148.85 149.07 149.07 148.83
14 28.99 112.61 112.29 112.30 112.60
15 28.86 18.56 18.59 18.58 18.54
16   28.28 28.04 28.05 28.13
17   42.85 42.84 42.83 42.85
18   71.46 71.47 71.46 71.46
19   29.30 29.30 29.28 29.30
20   28.88 28.86 29.00 28.99
1′ 133.91 132.32 132.30 133.92 133.92
1′a 129.50 130.39 130.20 129.51 129.52
2′ 155.84 156.31 156.35 155.84 155.84
3′ 122.06 121.70 121.81 122.06 122.05
4′ 129.97 129.95 129.98 129.97 129.95
4a′ 131.07 130.94 131.10 131.25 131.25
5′ 156.81 156.73 156.74 156.88 156.79f
5a′ 118.00 118.15 118.12 118.01 118.01
6′ 107.65 107.62 107.60 107.65 107.60g
7′ 157.65 157.44 157.78 157.85 157.60e
8′ 121.19 120.83 120.96 121.17 121.06c
8a′ 131.23 131.14 130.94 131.09c 131.25h
9′ 192.01 n. o. 192.38 191.98d 191.96d
10′ 192.77 192.06 193.57 192.67 192.68
11′ 23.07 31.26 31.24 23.06 23.07
12′ 44.21 50.13 50.02 44.21 44.22
13′ 71.98 148.85 149.07 71.98 71.98
14′ 28.99 112.61 112.29 28.86 28.88
15′ 28.86 18.56 18.59 28.86 28.88
16′   28.28 28.04    
17′   42.85 42.84    
18′   71.46 71.47    
19′   29.30 29.30    
20′   28.88 28.86    
7-OCH3, 56.29 56.27 56.28 56.28 56.28
7′-OCH3 56.29 56.27 56.28 56.28 56.28
a

125 MHz.

b

175 MHz; n.o. not observed.

c,d,e,f,g,h

Signals in each column are interchangeable.