Table 1. 13C NMR Data of Compounds 1–5 (Methanol-d4, T = 298 K, δ ppm).
| position | 1a | 2b | 3b | 4b | 5b |
|---|---|---|---|---|---|
| 1 | 133.91 | 132.32 | 132.30 | 132.29 | 132.30 |
| 1a | 129.50 | 130.39 | 130.20 | 130.21 | 130.37 |
| 2 | 155.84 | 156.31 | 156.35 | 156.35 | 156.31 |
| 3 | 122.06 | 121.70 | 121.81 | 121.81 | 121.69 |
| 4 | 129.97 | 129.95 | 129.98 | 129.97 | 129.95 |
| 4a | 131.07 | 130.94 | 131.10 | 131.09 | 130.95 |
| 5 | 156.81 | 156.73 | 156.74 | 156.75 | 156.71f |
| 5a | 118.00 | 118.15 | 118.12 | 118.13 | 118.13 |
| 6 | 107.65 | 107.62 | 107.60 | 107.65 | 107.67g |
| 7 | 157.65 | 157.44 | 157.78 | 157.61 | 157.47e |
| 8 | 121.19 | 120.83 | 120.96 | 120.97 | 120.95c |
| 8a | 131.23 | 131.14 | 130.94 | 130.95c | 130.91h |
| 9 | 192.01 | n. o. | 192.38 | 192.44d | 192.68d |
| 10 | 192.77 | 192.06 | 193.57 | 193.68 | 193.81 |
| 11 | 23.07 | 31.26 | 31.84 | 31.22 | 31.25 |
| 12 | 44.21 | 50.13 | 50.02 | 50.04 | 50.12 |
| 13 | 71.98 | 148.85 | 149.07 | 149.07 | 148.83 |
| 14 | 28.99 | 112.61 | 112.29 | 112.30 | 112.60 |
| 15 | 28.86 | 18.56 | 18.59 | 18.58 | 18.54 |
| 16 | 28.28 | 28.04 | 28.05 | 28.13 | |
| 17 | 42.85 | 42.84 | 42.83 | 42.85 | |
| 18 | 71.46 | 71.47 | 71.46 | 71.46 | |
| 19 | 29.30 | 29.30 | 29.28 | 29.30 | |
| 20 | 28.88 | 28.86 | 29.00 | 28.99 | |
| 1′ | 133.91 | 132.32 | 132.30 | 133.92 | 133.92 |
| 1′a | 129.50 | 130.39 | 130.20 | 129.51 | 129.52 |
| 2′ | 155.84 | 156.31 | 156.35 | 155.84 | 155.84 |
| 3′ | 122.06 | 121.70 | 121.81 | 122.06 | 122.05 |
| 4′ | 129.97 | 129.95 | 129.98 | 129.97 | 129.95 |
| 4a′ | 131.07 | 130.94 | 131.10 | 131.25 | 131.25 |
| 5′ | 156.81 | 156.73 | 156.74 | 156.88 | 156.79f |
| 5a′ | 118.00 | 118.15 | 118.12 | 118.01 | 118.01 |
| 6′ | 107.65 | 107.62 | 107.60 | 107.65 | 107.60g |
| 7′ | 157.65 | 157.44 | 157.78 | 157.85 | 157.60e |
| 8′ | 121.19 | 120.83 | 120.96 | 121.17 | 121.06c |
| 8a′ | 131.23 | 131.14 | 130.94 | 131.09c | 131.25h |
| 9′ | 192.01 | n. o. | 192.38 | 191.98d | 191.96d |
| 10′ | 192.77 | 192.06 | 193.57 | 192.67 | 192.68 |
| 11′ | 23.07 | 31.26 | 31.24 | 23.06 | 23.07 |
| 12′ | 44.21 | 50.13 | 50.02 | 44.21 | 44.22 |
| 13′ | 71.98 | 148.85 | 149.07 | 71.98 | 71.98 |
| 14′ | 28.99 | 112.61 | 112.29 | 28.86 | 28.88 |
| 15′ | 28.86 | 18.56 | 18.59 | 28.86 | 28.88 |
| 16′ | 28.28 | 28.04 | |||
| 17′ | 42.85 | 42.84 | |||
| 18′ | 71.46 | 71.47 | |||
| 19′ | 29.30 | 29.30 | |||
| 20′ | 28.88 | 28.86 | |||
| 7-OCH3, | 56.29 | 56.27 | 56.28 | 56.28 | 56.28 |
| 7′-OCH3 | 56.29 | 56.27 | 56.28 | 56.28 | 56.28 |
125 MHz.
175 MHz; n.o. not observed.
Signals in each column are interchangeable.