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. 2020 Feb 6;21(9):1285–1287. doi: 10.1002/cbic.201900716

Scheme 2.

Scheme 2

Synthesis of pro‐N6azA probe. a) 2‐Azidoethylamine, Et3N, EtOH, 60 °C, overnight, 90 %; b) Me2C(OMe)2, 10 % TsOH, acetone, RT, 2 h, 74 %; c) benzyl (chloro(phenoxy)phosphoryl)alaninate, tBuMgCl, THF, RT, overnight, 74 %; d) 90 % TFA, RT, 1 h, 89 %.