Table 2.
| ||||||
---|---|---|---|---|---|---|
Entry |
Catalyst [mol %] |
T [°C] |
p [bar][b] |
t [h] |
Conv. [%][c] |
Chemoselectivity 11 [%][c] |
1 |
A (2)+[Bu4N]Br (3) |
120 |
75 |
4 |
97 |
84 |
2 |
A (2) |
120 |
75 |
4 |
78 |
69 |
3 |
[Bu4N]Br (3) |
120 |
75 |
4 |
60 |
88 |
4 |
none |
120 |
75 |
4 |
0 |
– |
[a] Reaction conditions: 10 (6.3 mmol), biphenyl (10 mol %) as an internal standard. [b] Pressure of CO2 at 40 °C. [c] Derived from quantitative 1H NMR spectroscopy.