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. 2020 May 18;59(25):9856–9867. doi: 10.1002/anie.202000940

Table 1.

Radiative (k r) and non‐radiative (k nr) transition rates of each regioisomer in solution and colloidal suspensions (THF:H2O=1:9).

THF solution

Colloidal suspension[a]

k r [106 s−1]

k nr [106 s−1]

k r [106 s−1]

k nr [106 s−1]

1,4‐isomer

25

76

24

30

9,10‐isomer[b]

50

250

53

109

1,5‐isomer

67

20

49

360

1,8‐isomer

48

20

31

170

2,6‐isomer

54

7.2

43

250

[a] Rate constants were calculated based on amplitude‐averaged lifetimes. [b] The N,N‐dipropylamine analogue of 9,10‐BPA was used because the Φ fl of 9,10‐BPA (0.02) is too small to derive reliably accurate rate constants.