Table 1.
|
THF solution |
Colloidal suspension[a] |
||
---|---|---|---|---|
|
k r [106 s−1] |
k nr [106 s−1] |
k r [106 s−1] |
k nr [106 s−1] |
1,4‐isomer |
25 |
76 |
24 |
30 |
9,10‐isomer[b] |
50 |
250 |
53 |
109 |
1,5‐isomer |
67 |
20 |
49 |
360 |
1,8‐isomer |
48 |
20 |
31 |
170 |
2,6‐isomer |
54 |
7.2 |
43 |
250 |
[a] Rate constants were calculated based on amplitude‐averaged lifetimes. [b] The N,N‐dipropylamine analogue of 9,10‐BPA was used because the Φ fl of 9,10‐BPA (0.02) is too small to derive reliably accurate rate constants.